The Barcelona star was shown a straight red card by the referee ater the final whistle after previously already receiving his second yellow of the tournament
After the full-time whistle, Neymar kicked the ball at Colombia’s Pablo Armero and was subsequently confronted by Murillo, who scored the first-half winner for Colombia.
Neymar thrusted his head towards Murillo, but was then pushed violently in the back by Bacca as players from both teams gathered to break up the argument.
The referee consequently opted to show the Barcelona man a red card, while Bacca received the same punishment for his role in the incident.
Brazil will thus have to make do without the services of their skipper in their final Group C encounter versus Venezuela due to suspension.
The forward had previously already picked up his second yellow card of the group stages and would have missed the match against Venezuela without his dismissal, too.
The Selecao skipper was cautioned in his side's 2-1 win over Peru on matchday one for scraping away the referee's vanishing spray ahead of a free kick and again went into the referee's book in Santiago for handling the ball.
The 23-year-old played a vital role in his side's win over Peru, scoring once and setting up the winner for Douglas Costa well into stoppage time, but as unable to make an impact against Colombia.
The Barcelona man's absence at the Monumental in Santiago could see one of Douglas Costa, Philippe Coutinho or Robinho make their way into the starting XI.
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